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Shrunk836 I've been having internet issues too but with no connection on any secondary profiles. I have ProtonVPN basic service, so I have to disconnect before switching profiles and then reconnect. I couldn't get an internet connection on secondary profiles, but on the main profile and work profile (using Shelter on the main profile), it worked fine. It didn't matter if I was on mobile or Wi-Fi, VPN on or off, "Always on" on or off, or kill swith on or off. There was no connection even though GOS indicated that everything was connected.
After a couple of days of pulling my hair out, last night I changed the "Internet connectivity checks" from GrapheneOS to Off, and it fixed it for some reason, but today I had no connection again. After fiddling with it some more, I finally narrowed it down to the kill switch in the main profile. It seems that that setting and VPN connection status in the main profile are now global. The "Always on" setting can be either on or off, but if it and the kill switch are on and I disconnect the VPN and switch profiles, the secondary profile has no internet regardless of any settings in that profile. I think this started with the update.