Uphill1945
I'm assuming you're asking if it's possible to restrict network access to apps based on the kind of network you're connected to? If so, then no, there is no way to do that in GrapheneOS.
For many who want to preserve their privacy, using a VPN all the time should be sufficient, even if connectivity stays the same across different networks. Or, as Hulk suggested, just turn off mobile data in the network settings.