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Glad you found the solution. I did not use an app myself so that's probably where the differing views came from, i prefer to do what i can nativly in the os. and adding networks by QR is possible
Just for information. you can add networks from QR codes nativly in the OS on any profile by going to SYSTEM > Network & Internet > Internet > and there is a add network button under the found wifi points. if you click it there is a QR icon next to the box to enter the WiFi name :)
Networks added native can only be removed in owner profile from my experience no matter what profile you add them in. i think its a safety feature.
As for the app. I wonder if it would keep doing that if you did not log into the secondary profile after a restart and tried. seems like it took control over your WiFi settings.