mine21 It is possible that Google isn't supporting VoLTE on XPhone because there is a problem with XPhone's implementation of VoLTE, perhaps some disagreement between Google's cellular modem firmware and XPhone's system. If something like that is going on, I don't think the GrapheneOS project is in a position to do much, especially without a way to test against XPhone cell sites.
The GrapheneOS carrier overrides can help users when the sole issue is that Google's carrier configurations are blocking VoLTE use that would otherwise work fine. If there is an actual problem, the overrides can't fix it.
I wish I had better news...
Please note that I do not speak for the GrapheneOS project.