Boyz You need to enable VoLTE/VoNR (not sure if there are separate toggles, my carrier only has VoLTE support), to allow calls to be made over 4G/5G networks.
Your carrier might support it and enable it for your line but the toggle won't show anyway, in that case you can find some way to force enable it and it might work, though any method I'm aware of is insecure and inconvenient so I don't know if it's worth it.